3d-Nitrogen MOFs Linkers

The charged nitrogen-donating linkers are usually azoles, which are commonly used to prepare porous coordination polymers. The azolyl-rich ligands provide not only an energy source but also rich bridging modes for the 3D-enhanced structures. The physical dimensions (1D, 2D, and 3D) of high-energy MOF structures are closely related to sensitivity and performance, as high-dimensional structures will provide diversity of coordination modes and high structural stability. Compared to 1D and 2D architectures, 3D frameworks have the most rigid and enhanced structures due to the most complex coordination patterns, which further improves stability. In addition to physical size, the sensitivity of ligands can also affect the stability of energetic MOFs. Therefore, choosing more stable nitrogen-rich ligands to replace hydrazine and azide would be a favorable route to construct safer energetics. Among all nitrogen-rich ligands, the five-membered heterocyclic building block can generate higher heat of formation and is coordinated by abundant lone pair electrons on the ring. In addition, the effect of the azole ring can prolong the structure, resulting in multi-dimensionality. Therefore, high-performance MOFs can be obtained by using 3d-Nitrogen MOFs linkers as the composite material of MOFs.

CD Bioparticles manufactures and supplies 3d-Nitrogen MOFs linkers for MOFs synthesis. Contact us to find out how 3d-Nitrogen MOFs linkers can help you in your work.

1,3,5-tris (pyridin-4-ylethynyl)benzene

Catalog: CDM-CH1064

MW: 381.4281

CAS No.: 168289-78-9

1,3,5-tris (pyridin-4-ylmethoxy)benzene

Catalog: CDM-CH1050

MW: 399.44184

CAS No.: 915002-24-3


Catalog: CDM-CH1025

MW: 476.57046

CAS No.: 1366291-62-4

1,2,4,5-Tetrakis (Imidazol-1-Ylmethyl)Benzene

Catalog: CDM-CH1009

MW: 398.46368

CAS No.: 475094-90-7

1,3,5-tri (1H-iMidazol-1-yl)benzene

Catalog: CDM-CH1053

MW: 276.29598

CAS No.: 528543-96-6

1,3,5-tri (1H-tetrazol-5-yl) benzene

Catalog: CDM-CH1008

MW: 282.22434

CAS No.: 193614-99-2


Catalog: CDM-CH1059

MW: 510.51222

CAS No.: 1006608-03-2

1,3,5-Triazine, 2,4,6-tri-1H-imidazol-1-yl

Catalog: CDM-CH1031

MW: 279.26016

CAS No.: 14445-75-1

1,3,5-Trimethyl-2,4,6-Tris (4-pyridyl)benzene

Catalog: CDM-CH1056

MW: 351.44364

CAS No.: 2027486-17-3

1,3,5-tris ( (1H-imidazol-1-yl)methyl)benzene

Catalog: CDM-CH1061

MW: 318.37572

CAS No.: 147951-02-8

1,3,5-tris (4-(4H-1,2,4-triazol-4-yl)phenoxy)benzene

Catalog: CDM-CH1067

MW: 555.54624

CAS No.: 1680199-77-2

1,3,5-Tris (4-Pyridyl)Benzene

Catalog: CDM-CH1028

MW: 309.3639

CAS No.: 170165-84-1

1,3,5-tris (N-imidazolylmethyl)-2,4,6-trimethylbenzene

Catalog: CDM-CH1029

MW: 360.45546

CAS No.: 220593-43-1

1,​3,​5-​tris (p-​imidazolylphenyl)​benzene

Catalog: CDM-CH1044

MW: 504.58386

CAS No.: 1386857-85-7

2,2': 6',2''-Terpyridine-4'-Carbaldehyde

Catalog: CDM-CH1042

MW: 261.27804

CAS No.: 108295-45-0

2,4,6-tris (3,5-dimethylpyrazol-1-yl)-1,3,5-triazine

Catalog: CDM-CH1054

MW: 363.41964

CAS No.: 154403-27-7


Catalog: CDM-CH1051

MW: 360.32628

CAS No.: 2230253-24-2


Catalog: CDM-CH1049

MW: 316.35984

CAS No.: 55391-41-8

4'-(4'''-pyridyl)-1,2': 6'1''-bis (pyrazolyl)pyridine

Catalog: CDM-CH1058

MW: 288.30668

CAS No.: 918959-39-4

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